Uranium-lead dating is an ancient and sophisticated radioactive dating technique with important significance in geology and archaeology. This method can accurately determine the age of rocks ranging from one million years old to more than 4.5 billion years old, typically with an accuracy range of 0.1-1%. The uranium-lead dating method is most commonly applied to zircon, a mineral that absorbs uranium and thorium during its formation but strongly rejects lead. This means that there is no lead inside newly formed zircon crystals and any lead found is radioactively generated. Therefore, by measuring the ratio of lead to uranium, the age of zircons can be reliably determined.
Uranium decays into lead via two different decay chains: 238U decays into 206Pb, and 235U decays into 207Pb.
Uranium is converted to lead through a series of alpha and beta decays, with 238U and its daughter nuclides undergoing a total of eight alpha decays and six beta decays, while 235U and its daughter nuclides undergo only seven alpha decays and four beta decays. Sub-beta decay. The existence of two "parallel" uranium-lead decay pathways allows for multiple possible dating techniques within the entire U-Pb system.
While zircon (ZrSiO4) is the most commonly used mineral, other minerals such as monotactinite, titanite, and baddeleyite can also be used for uranium-lead dating. At the same time, some common carbonate minerals such as calcite and aragonite can also be dated using uranium-lead dating technology when crystals containing uranium and thorium cannot be obtained. Although the ages of these minerals are generally less precise than those of the magmatic and metamorphic minerals traditionally used for age dating, they are more common in the geological record.
During the alpha decay process, zircon crystals undergo radiation damage that is primarily localized around the parent isotopes (uranium and thorium). These damages will dislodge the daughter isotope (lead) from its original position in the zircon lattice. When the concentration of the parent isotope is high, the damage to the crystal lattice can be quite severe and often links up into a network of radiation damage, further aggravating the destruction within the crystal. These radiation-damaged shrinkage and microcracks can lead to the leaching of lead isotopes.
In the absence of loss or gain of external lead, the age of zircons can be calculated by assuming exponential decay of uranium. This calculation ignores the lead produced in the background radiation and relies only on the decay rate of uranium. If a series of zircon samples lost different amounts of lead, an inconsistent tie line would form. This inconsistency poses a challenge to determining the age of each decay system.
Clair Cameron Patterson, an American geochemist who pioneered the uranium-lead radiometric dating method, first estimated the age of the Earth in 1956 to be 4.55 billion years, and this A figure that remains unchallenged to this day.
Our understanding of the age of the Earth has benefited from the development of uranium-lead dating. But as technology advances, can we get closer to uncovering the beautiful secrets of Earth or other planets?