In the search for more environmentally friendly and economical alternatives, sodium-ion batteries (NIBs) have gradually attracted global attention. As sodium becomes cheaper to procure relative to lithium and is more geographically widespread, sodium-ion batteries are emerging as a strong contender for next-generation energy storage technology.
Over the past few years, the price of lithium has continued to rise, attracting many researchers to turn to sodium-ion technology, making sodium a potential alternative.
According to reports, the development of sodium-ion batteries began as early as the 1970s, but was once neglected due to the rapid development of lithium-ion batteries. After entering the 2010s, sodium-ion batteries began to attract attention from the industry again due to the rising cost of lithium materials and the need for environmental protection.
Sodium is extremely abundant on Earth, especially in seawater, which is the fundamental reason why sodium-ion batteries have the potential to replace lithium-ion batteries. In addition, sodium-ion batteries use cheaper raw materials such as iron to replace precious metals such as cobalt and nickel, which further reduces the environmental burden of construction.
If sodium is used to replace lithium, the cost of sodium-ion batteries can be greatly reduced, which will be a revolution in the energy storage market.
Sodium-ion batteries operate in a similar way to lithium-ion batteries. During discharge, sodium ions move from the positive electrode to the negative electrode while electrons flow through an external circuit, and the opposite happens during charging. Sodium has a larger ionic radius, which makes its intercalation kinetics not as fast as lithium in some cases, but it still exhibits impressive performance.
Although sodium has a slower intercalation rate, its capacity is comparable to that of lithium in many materials.
Sodium-ion batteries are unique in that they use materials that have different strengths and physical and electrochemical properties. Current research focuses on materials such as nitrogen-doped hard carbon, carbon arsenic, metal alloys, and even oxide materials for negative and positive electrodes. New research is also exploring free and fire-free electrolytes.
Among them, hard carbon, as the negative electrode material, shows amazing stability and high specific capacity. Many advanced technologies are exploring how to improve the energy density and cycle stability of sodium-ion batteries to achieve the goal of commercialization.
Compared with lithium-ion batteries, sodium-ion batteries have demonstrated their low cost and environmental protection advantages in long-term market applications.
With the participation of some well-known companies, the commercialization process of sodium-ion batteries is accelerating. Chinese companies such as CATL and BYD are working hard to advance the research and development of sodium-ion batteries, hoping to launch market-ready products in the near future. Public grid energy storage and the electric vehicle market are both areas where sodium-ion batteries may enter.
In 2023, traditional battery industry experts have predicted that sodium-ion batteries will become the mainstream energy storage technology for the next decade.
The development of sodium-ion batteries is not only subject to changes in market demand, but is also closely related to the promotion of technology, market acceptance, and fluctuations in raw material costs. Whether sodium-ion batteries can truly replace lithium-ion batteries in the future depends on technological breakthroughs and the expansion of their applications. Let us think together about what changes the development of this emerging battery will bring to our lives.