Water splitting technology is like giving water a kind of magic that can convert it into hydrogen and oxygen. This process is not only ubiquitous in nature, but is also a core technology for the future hydrogen economy. However, in practical applications, water decomposition is full of challenges, especially how to obtain hydrogen efficiently and economically, which is the research focus of many scientists and engineers.
Water electrolysis is the process of splitting water (H2O) into oxygen (O2) and hydrogen (H2). The process is simple but challenging because the electricity required often exceeds the economic value of the hydrogen itself.
Although low-temperature electrolysis has a low efficiency, high-temperature electrolysis (HTE) has the potential to increase energy conversion efficiency to about 50%.
This is because high-temperature electrolysis uses some of the heat energy in the chemical reaction, so the energy converted is more efficient. With advances in electrolysis technology, it will be possible to achieve more efficient hydrogen production in the future.
Another form of water splitting can be seen in the process of photosynthesis, but in this process, the electrons produced are not ultimately used to produce hydrogen, but are used to reduce carbon dioxide and produce sugars. The "oxidation of water" in this process can be called the decomposition of water in nature. In this process, the manganese element at the active site has attracted a lot of research on the synthesis of manganese compounds as water oxidation catalysts.
Water splitting using electricity produced by photovoltaic systems is considered one of the cleanest ways to produce hydrogen. In a photoelectrochemical cell, solar energy is used to drive the splitting of water while simultaneously performing catalysis, which is known as artificial photosynthesis.
In contrast, water splitting using photocatalysts suspended in water could be more efficient. This type of technology aims to shorten the entire reaction process to a single step to produce hydrogen and oxygen.
In addition to the above methods, there is also the radiation dissociation method using nuclear radiation. This method is based on the hydrogen produced in areas of high radiation. A study discovered a microbial community in a gold mine in South Africa that specializes in producing hydrogen from radiation.
Thermal water decomposition (pyrolysis) faces challenges of high temperature and material limitations in industrial applications. Although some water molecules will begin to decompose at 2200°C, the energy and materials required for such high temperatures are relatively expensive.
The potential of nuclear energyNuclear plants are designed with the flexibility to generate electricity during the day and hydrogen at night, allowing them to better match electricity demand. If the production cost of hydrogen can be reduced significantly, it will become another option to compete with existing grid energy storage technologies.
For example, Hydrosol II, built at the Plataforma Solar de Almería in Spain, demonstrates the technology to use concentrated solar energy to reach the necessary temperatures of up to 1200°C. The facility is designed using a modular concept, giving it the potential to be expanded to megawatt-scale hydrogen production.
Thermochemical processes such as the sulfur-iodine cycle show potential for hydrogen production, and the heat energy sources for these methods are mainly solar and thermal energy. The development of these technologies has the potential to break through the efficiency limitations of traditional water electrolysis methods.
Water decomposition is not only a part of technological innovation, but also related to the sustainability of future energy. As we watch this water-splitting magic, we can't help but wonder, can these advanced technologies revolutionize the way we think about energy production?