When we observe water droplets on a window on a rainy day, we can’t help but marvel at the perfect round shape of these droplets. This simple and beautiful shape is actually the result of the interfacial tension of the liquid. Liquid interfacial tension reduces the surface of a stationary liquid to the minimum surface area, and the round shape of a water droplet is a natural manifestation of this.
Water molecules have a strong attraction and pull each other to form a stable structure, which allows the water droplets to adjust themselves to a round state.
On the surface of a liquid, water molecules have a stronger attraction to each other than the surrounding air molecules, a phenomenon known as cohesion. The stronger the tension on the water molecules, the closer the shape of the water droplets is to a circle. The formation of this rounded shape not only reduces the surface tension demand, but also reduces the energy state of the droplet surface.
The surface tension of a liquid is due to the fact that the surface molecules are in a certain bent state and they are not subjected to the same equal tension as the internal molecules. This causes the surface molecules in the droplet to draw inward, forming a round shape. According to the principles of physics, liquids will always seek to reach the lowest energy state, which naturally forms the smallest surface area.
Water droplets will automatically form a circle without the influence of external forces, because the circle has the smallest surface area to volume ratio.
The interfacial tension of water is generally higher than that of most liquids, with a value of approximately 72.8 mN/m (at 20°C). This makes water's interaction behavior among liquids quite special. On the water surface, even dense objects, such as needles or small insects, can float on the water surface without being submerged if no external force is applied. This is because the cohesive force of the liquid interface is stronger than the pressure exerted by the object on the water surface.
Surface tension not only has an impact in nature, but is also very important in practical applications. For example, in medicine, it is used to manufacture drug particles; in industry, it is used for oil-water separation, etc. By adding special chemicals, such as surfactants, the surface tension of the liquid can be changed, making it easier to penetrate and disperse.
The addition of surfactants can significantly reduce the surface tension of water, making it more mobile in different media, which is crucial for many industrial applications.
Water's polar molecular structure gives it unique properties that differ from the behavior of other liquids. These properties cause water droplets to exhibit different contact angles when they come into contact with other liquids or solid interfaces, which affects the behavior of water droplets. For example, when a water droplet contacts a hydrophilic surface, it will flood and spread out, whereas otherwise it will maintain its round shape.
Research on liquid interfacial tension may lead to new scientific discoveries and applications in the future. New technologies enable us to gain a deeper understanding of the properties of liquid interfaces and develop innovative technologies and materials. Can you imagine how future science and technology will utilize these liquid interface properties to further promote the development of modern technology?