A quantum well is a special kind of potential well that has only discrete energy values. In this model, particles are confined to a two-dimensional plane region, resulting in quantum confinement effects. When the thickness of the quantum well is close to the de Broglie wavelength of the carriers (usually electrons and holes), the electrons will only be able to have discrete energy values, forming so-called "energy sub-bands". The concept was first proposed independently by Herbert Kroemer and Zhores Alferov and R.F. Kazarinov in 1963. Over time, quantum wells have found widespread use in semiconductor physics.
Since 1970, the study of shallow wells and layered structures has attracted the attention of many scientists and stimulated the rapid development of semiconductor optoelectronic devices.
The development of semiconductor quantum wells began in 1970, when Esaki and Tsu, the inventors of shallow wells and layered structures, proposed that heterostructures formed by semiconductors with different band gaps could show interesting and Practical nature. With the advancement of science and technology, especially the advancement of crystal growth technology, the requirements for high purity and few defects of these structures have led to the birth of many quantum well devices.
Quantum wells are typically formed by sandwiching one material, such as gallium arsenide, between two layers of a material with a wider bandgap, such as aluminum phosphide. The growth methods currently used mainly include molecular beam epitaxy and chemical vapor deposition, and the layer thickness can be as fine as a single layer. In these material systems, a quantum well is formed whose properties are closely related to the materials on either side. According to different growth methods, the structure of quantum well can be divided into lattice matching system, strain balance system and strain system.
These technological advances should not be underestimated because they make more sophisticated semiconductor devices possible.
Inside a quantum well, particles exist in discrete energy eigenstates. Taking the gallium arsenide-aluminum arsenide structure as an example, the energy level of electrons in this structure is lower than that of the surrounding materials. This structure causes the electrons to be bound and unable to move freely. The state of particles in the well is similar to that of "particles in a box", which restricts their movement and allows them to operate only at specific energy levels.
Quantum wells and their devices are a subfield of solid-state physics that is still under extensive research. The theory of these systems is based on important results from several fields including quantum physics, statistical physics and electrodynamics. The simplest model is the infinite well model, in which the boundary of the potential well is assumed to be infinite. Although this model is a theoretical simplification, it provides some insights into the physics of quantum wells.
Although the infinite well model is helpful in understanding energy states, the number of energy states it actually predicts is usually greater than the actual situation. This is because the actual potential well boundary is not infinite, but finite. The finite well model provides a more realistic description, assuming that the boundary of the potential well is finite, which will allow the wave function to penetrate into the barrier region, thereby more accurately predicting the energy behavior in the quantum well.
With the in-depth study of quantum wells and their properties, this knowledge has been widely used in modern electronics, including the development of electronic components such as light-emitting diodes and transistors, as well as their application in optoelectronic technology and communication equipment. The development of quantum wells is closely linked upstream and downstream, allowing the scientific community to gradually recognize the potential of this field and continue to explore further innovations.
Many experts believe that future quantum technology and materials science will bring us more unexpected applications.
The development of quantum well technology tells us that the operating rules of the microscopic world are not only mysterious, but also full of infinite possibilities. How many unsolved mysteries will be waiting for us to explore in the future?