Against the backdrop of increasing global energy demand, the value of agricultural waste has gradually attracted attention. Plant residues such as corn residues and sugarcane bagasse, as the most abundant biomass raw materials, can not only provide potential resources for the production of biofuels, but also help achieve sustainable development. The chemical composition of these agricultural wastes, which are rich in cellulose, hemicellulose and lignin, makes them challenging to produce biofuels, but also offers endless possibilities.
"The presence of these three components makes the processing of lignocellulose very challenging, and the key to overcoming this resistance lies in a combination of thermal, chemical, enzymatic and microbial processes."
Lignocellulose consists of three main components: cellulose, hemicellulose and lignin, each with its own unique properties that make commercial applications challenging. Lignin is a heterogeneous polymer composed of multiple monomers and has a high degree of cross-linking characteristics. Hemicellulose, on the other hand, consists of branched polysaccharides that are often covalently linked to lignin via phenolic acids, which makes it difficult to extract sugars for conversion into biofuels. In addition, cellulose is a homopolymer of glucose with extremely low solubility, and glucose usually needs to be extracted through chemical or biological degradation.
Many crops are of interest for their ability to provide high yields of biomass. Some crops can be harvested several times a year, such as poplar and giant ton grass. As the preferred energy crop, sugarcane not only provides fermentable sucrose, but also produces a waste material rich in lignocellulose - bagasse.
"Lignocellulosic biomass has a long history as a wood fuel, but in recent decades, interest in it as a precursor to liquid fuels has grown."
Lignocellulosic biomass is the main raw material for the pulp and paper industry. Chemical pulp is produced by separating lignin and hemicellulose to leave the cellulose component. Most lignin is removed during pulp processing as a waste product for use as fuel, which offers the potential for current paper mills to be repurposed for the production of lignocellulosic sugars.
With the rising demand for renewable energy, lignocellulosic biomass holds great promise for use in biofuel production. Converting lignocellulose into bioethanol is an attractive alternative as a way to combat fossil fuels. In addition, there are a variety of other fuels derived from lignocellulose, such as butanol, dimethylfuran, and gamma-ketovalerolactone.
"However, the resistance of lignocellulose to degradation makes the process of extracting fermentable sugars face many challenges. How to efficiently separate and extract these sugars remains the focus of current research."
Currently, various chemicals may be obtained from lignocellulosic biomass, especially in the production of biocomposites, with claimed sustainability. Herbaceous and agricultural byproducts such as invasive plants and agricultural waste offer possible alternative sources for the creation of new “green” composite materials.
"As a renewable and cheap alternative material, cellulose is gaining wide attention in the industry, and its future development cannot be underestimated."
With the advancement of technology and the emphasis on environmental protection, converting agricultural waste into valuable resources has not only become possible, but can also provide a solution to global energy needs. Can we rely entirely on agricultural waste for a sustainable future?