Electron diffraction is a broad term covering the phenomenon of electron beams changing direction due to elastic interactions with atoms. The basic principle is that when electrons propagate in an electric field, the electrons will undergo elastic scattering due to their Coulomb force interaction with the positively charged nucleus and surrounding negatively charged electrons in the atom. This process does not change the energy of the electrons. The mapping formed from the direction of electrons far away from the sample is called a diffraction pattern. These patterns not only help understand the atomic structure of the material, but also play an important role in image comparison in electron microscopy.
The wave nature of electrons allows them to diffract and interact with matter, revealing its secret structure.
The use of electrons has a long history. The understanding and control of electrons in vacuum in the 19th century, combined with the development of electron waves in the early 20th century, jointly led to the birth of electron microscopy and diffraction technology. This technology developed rapidly from 1920 to 1935. With the deepening of this basic work, electron diffraction technology also saw many methodological and technological innovations.
The most common electron diffraction method is to transmit electrons through a thin sample. The thickness of the sample is usually between 1 nanometer and 100 nanometers, depending on the arrangement of atoms in the material, such as single crystal, polycrystalline or different types. solid. The diffraction pattern corresponding to each arrangement also has its own characteristics. Researchers can collect this diffraction information through a variety of different illumination methods, such as parallel illumination, focused beams, or rotating and scanning the electron beam, all of which make interpretation of the information easier.
Electron diffraction patterns can also be used to characterize molecules and can analyze gases, liquids and surfaces with varying degrees of precision.
Although similar to X-ray and neutron diffraction, electron diffraction is far less accurate in predicting simple models. Basic geometric models can provide an idea of the intensity in a diffraction pattern, but obtaining accurate intensity and diffraction spot positions requires more complex dynamic diffraction methods. This means that understanding the wave properties and interactions of electrons is critical to using electron diffraction accurately.
Dating back to ancient Greece, the concept of electrons originated from "amber" and the ancients' observations of static electricity. Over time, people came to understand how electrons behave in a vacuum, a process that led to significant technological advances. In the 1870s, scientists began experiments using vacuum tubes that eventually led to the use of electron beams and their application in electron microscopy and measurement technology.
With the development of electron wave theory and quantum mechanics, scientists have gradually uncovered the mystery of how electrons diffract as waves.
In 1924, Louis de Broglie proposed in his doctoral thesis that electrons and other matter could actually be considered waves. Later, this concept was confirmed in the framework of quantum mechanics, laying a theoretical foundation for the development of electron diffraction technology.
The emergence of the electron microscope is a major progress in the study of electron diffraction. As early as 1931, Max Knorr and Ernst Ruska successfully built the first electron microscope capable of producing magnified images. This technology allows scientists to observe the structure of the microscopic world, opening up a new field of research.
Breaking through the limitations of traditional optics, the development of electron microscopes has provided powerful tools for many fields such as materials science and biology.
As time goes by, the combination of electron microscopy and diffraction technology continues to achieve innovation. New numerical algorithms and imaging technologies allow researchers to obtain information about the sample structure in a more precise way, which also leads the way in the development of complex materials. and polymer research progress.
Electron diffraction technology has gradually transformed from early qualitative analysis to today's quantitative analysis. This transformation is accompanied by the emergence of advanced numerical methods and innovative equipment. In the future, with the advancement of science and technology, electron diffraction will be able to provide more detailed structural information and promote further research in various fields.
As our understanding of electron wave properties and interactions deepens, can electron diffraction become one of the core technologies of materials science and nanotechnology in the future?