In today's scientific research, second harmonic generation (SHG), or frequency doubling, is gradually showing its importance in various applications. This phenomenon is not only a fundamental nonlinear interaction in optical systems, but is also found in many other systems, including electromagnetic waves, weather changes, or plasma physics. The essence of SHG is that two photons of the same frequency interact in a nonlinear material to synthesize a new photon with twice the energy of the original photon, while retaining the coherence of the excitation light.
The process of second harmonic generation is not only an important part of data communication, but also provides us with a tool to measure and explore the microscopic and macroscopic worlds.
The discovery of SHG dates back to 1961, when a group of scientists at the University of Michigan first demonstrated the process. They used the intense light from a ruby laser and focused it into a sample of quartz, producing light at 347 nanometers. The core of this technology lies in the use of nonlinear optical materials, which can efficiently convert the frequency of incident light under the right conditions.
The occurrence of SHG requires specific conditions, one of the key factors being the nonlinear optical properties of non-centrosymmetric media. In asymmetric crystals, the nonlinear response of light waves allows the photons to merge, thus generating a second harmonic. It is worth noting that in media with symmetry, this process is restricted, however, phenomena such as the Bloch-Siegert shift allow SHG to occur under certain circumstances.
In the case of high-intensity pulsed lasers, sometimes almost 100% of the light energy can be converted to the second harmonic frequency.
SHG can be realized in many ways, mainly divided into critical phase matching and non-critical phase matching. Critical phase-matched SHG involves combining photons at a specific crystal orientation, while noncritical phase-matched SHG is achieved by controlling the temperature of the crystal to tune the optical index.
In addition to its use in laser technology, SHG is also widely used in microscopy techniques in the biomedical field. By exploiting the properties of second harmonic generation, scientists can detect non-centrosymmetric materials such as collagen in cell structures or tissues. This allows us to achieve high-resolution imaging without the need for traditional aperture optics.
Advances in SHG technology have enabled researchers to reveal subtle structures and dynamic changes in life sciences.
Secondly, SHG is also used to measure ultrashort pulses because it can efficiently mix two optical pulses and generate the desired harmonic signals. This is crucial in modern optical measurements, especially in experiments in the fine time domain.
Whether in laser manufacturing, ultrashort pulse measurement or biological microscopy, SHG is closely related to our lives. With the continuous advancement of technology, we look forward to SHG demonstrating its unique power and potential in more application scenarios. Have you ever thought about how we can further exploit this phenomenon to improve science and medical technology in our daily lives in the future?