Benzene is an organic chemical compound with the molecular formula C6H6. This benzene molecule consists of six carbon atoms forming a planar hexagonal ring, with a hydrogen atom attached to each carbon atom. Since benzene contains only carbon and hydrogen atoms, it is classified as a hydrocarbon. It is one of the natural components of petroleum and one of the basic petrochemical products. The liquid benzene is colorless and highly flammable, and has a sweet smell that is partly responsible for the aroma of gasoline. Benzene is primarily used as a precursor in the manufacture of chemicals with more complex structures, such as ethylbenzene and culene, with annual production reaching billions of kilograms. Although benzene is a major industrial chemical, its use in consumer products is relatively limited due to its toxicity.
It is worth noting that benzene is classified as a carcinogen. The effects of long-term exposure continue to attract attention in media reports. For example, the New York Times reported that benzene pollution in the Boston area in 2022 posed dangers to multiple areas, and pointed out that benzene may eventually cause leukemia in some individuals.
The word benzene is derived from the fragrant resin of "colloidal benzene", a fragrant resin associated with Southeast Asia since ancient times. In 1825, Michael Faraday first isolated and identified benzene from the oily residue of coal gas production. In 1836, French chemist Auguste Laurent named this substance "phène", which became the origin of the words "phenol" and "phenyl". Benzene was first isolated from coal tar in 1845 by Charles Blackford Mansfield. Only a few decades later, the ring structure of benzene was determined, which was crucial for the development of organic chemistry.
"Benzene has a structure with six carbon atoms linked together, and its chemical properties affect the entire chemical system."
X-ray diffraction showed that all six carbon-carbon bonds in benzene are the same length, each about 140 picometers long. This intermediate length is due to electron delocalization, whereby the electrons of the C=C bond are evenly distributed among the six carbon atoms. The molecular structure of benzene exhibits a planar shape, and its stability contributes to its special chemical properties, known as aromaticity.
Many important compounds of benzene are derived by replacing one or more hydrogen atoms with other functional groups. Simple benzene derivatives include phenol, toluene, and aniline. The production of benzene is even more diversified in its application in the chemical industry, such as the manufacture of ethylbenzene. As market demand increases, global benzene production is also growing steadily.
"The annual production of benzene is extremely considerable, and most of the supply is used in the production of ethylbenzene, a precursor to plastics."
The main danger of benzene is its toxicity to the human body and its potential carcinogenicity. Long-term exposure to benzene may cause a series of health problems, including immune system suppression and blood system abnormalities. The presence of benzene in the environment is not limited to industrial operations, but also comes from products of daily life, such as gasoline and certain cleaning agents. The U.S. Environmental Protection Agency has also set strict limits on products containing benzene.
With the increasing global emphasis on environmental protection, the use of benzene faces many challenges. Many countries are looking for safer alternatives, especially in industrial and consumer goods. The future of benzene not only requires technological improvements to reduce the risk of its release into the environment, but also requires continued public attention to its hazards.
In the pursuit of progress, the impacts and risks posed by benzene make us reflect: Do we know enough about this chemical?