Advanced Materials Interfaces | 2019

Electronic Structure and Band Alignment of LaMnO3/SrTiO3 Polar/Nonpolar Heterojunctions

 
 
 
 
 
 
 
 
 
 

Abstract


Author(s): Kaspar, TC; Sushko, PV; Spurgeon, SR; Bowden, ME; Keavney, DJ; Comes, RB; Saremi, S; Martin, L; Chambers, SA | Abstract: © 2018 WILEY-VCH Verlag GmbH a Co. KGaA, Weinheim The behavior of polar LaMnO3 (LMO) thin films deposited epitaxially on nonpolar SrTiO3(001) (STO) is dictated by both the LMO/STO band alignment and the chemistry of the Mn cation. Using in situ X-ray photoelectron spectroscopy, the valence band offset (VBO) of LMO/STO heterojunctions is directly measured as a function of thickness, and found that the VBO is 2.5 eV for thicker (≥3 u.c.) films. No evidence of a built-in electric field in LMO films of any thickness is found. Measurements of the Mn valence by Mn L-edge X-ray absorption spectroscopy and by spatially resolved electron energy loss spectra in scanning transmission electron microscopy images reveal that Mn2+ is present at the LMO surface, but not at the LMO/STO interface. These results are corroborated by density functional theory simulations that confirm a VBO of ≈2.5 eV for both ideal and intermixed interfaces. A model is proposed for the behavior of polar/nonpolar LMO/STO heterojunctions in which the polar catastrophe is alleviated by the formation of oxygen vacancies at the LMO surface.

Volume 6
Pages 1801428-1801428
DOI 10.1002/ADMI.201801428
Language English
Journal Advanced Materials Interfaces

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