Interaction of Ultrathin Films of Ethylene Carbonate with Oxidized and Reduced Lithium Cobalt Oxide—A Model Study of the Cathode|Electrolyte Interface in Li‐Ion Batteries

Abstract

Aiming at a detailed, molecular scale understanding of the initial stages of the solid|electrolyte interphase (SEI) formation in Li-ion batteries,,we have investigated the interaction of the common electrolyte solvent component ethylene carbonate (EC) with fully lithiated LiCoO2 and reduced LiCoO2-δ films as model electrodes for the cathode. The results are compared with previous findings for pristine and lithiated highly oriented pyrolytic graphite, serving as model anode. Employing X-ray and ultraviolet photoelectron spectroscopy (XPS and UPS) measurements, we found that vapor deposition of EC on LiCoO2 and LiCoO2-δ at 80 K results in molecularly adsorbed EC, both in the monoand multilayer regime. XPS measurements detect significant changes of the adlayer between 170 and 255 K, indicating competing desorption and decomposition. Synchrotron based XPS measurements reveal a very similar decomposition pattern upon EC deposition on LiCoO2 at close to ambient temperatures. In both cases the remaining adlayer is mostly composed of Licontaining -C═O, -C‒O‒C-, -C‒H and -C‒Cmoieties such as Li2CO3, ROCO2Li, (CH2OCO2Li)2 and Li2O2. The activated decomposition of EC is caused by interaction with the oxide surface or, more specifically, with surface Li. This process can be considered as the initial stage of the chemical SEI formation.