High-efficiency TiO2/ZnO nanocomposites photocatalysts by sol–gel and hydrothermal methods

Abstract

TiO2/ZnO nanocomposites with ratio of Ti/Zn of 1:0, 1:1, 2:1, 3:1 and 0:1 was synthesized by sol–gel and hydrothermal methods. The performance and the photocatalytic of the nanocomposities mechanism were studied by X-ray diffractometer (XRD), Fourier transformed infrared (FT-IR), Brunauer–Emmett–Teller method (BET), Transmission Electron Microscopy (TEM), High-Resolution Transmission Electron Microscope (HRTEM) and UV–visible diffuse reflectance spectra (UV-Vis), respectively. The results showed that TiO2/ZnO nanocomposites successfully prepared at different Ti/Zn rations. HRTEM results clearly heterojunction structure, and it can reduce the band gap width of the composite and improve the optical absorption intensity. Besides, the degradation rate of methylene blue (MB) of TiO2/ZnO nanocomposites with a Ti/Zn ratio of 2:1 was close to 100% at 80\u2009min, which was better than the other four samples. The photocatalytic degradation reaction confirmed to the first-order kinetic equation. The kinetic constant of TiO2/ZnO nanocomposites with a ratio of 2:1 is 0.03748\u2009min−1, which is 2.8 times of pure ZnO and 4.8 times of pure TiO2, respectively. In addition, the major active species of the photocatalytic reaction are •OH and h+ through activity capture experiments. The improvement of the catalytic performance of TiO2/ZnO nanocomposites is mainly due to the ability to separate holes and electrons. High efficiency TiO2/ZnO photocatalysts are prepared by sol–gel and hydrothermal technology. Increase in catalytic efficiency due to the separation efficiency of electrons and holes. MB decolorization is not directly related to adsorption. The degradation of MB is a first order degradation kinetics. The major reactive species for photodegradation is the •OH. High efficiency TiO2/ZnO photocatalysts are prepared by sol–gel and hydrothermal technology. Increase in catalytic efficiency due to the separation efficiency of electrons and holes. MB decolorization is not directly related to adsorption. The degradation of MB is a first order degradation kinetics. The major reactive species for photodegradation is the •OH.