Couple of graphene oxide and functionalized carbon nanotubes for dye degradation enhancement of anatase under visible light and solar irradiation

Abstract

Graphene oxide sheets (GO) were coupled with carbon nanotubes (CNTs) to enhance the photoactivity of anatase under visible and solar irradiation. The carbon nanotube surface was functionalized in the acidic reflux condition before coupling with GO and decoration of anatase by the sol–gel method. A modified kinetic model was appropriately applied to predict the breakthrough in the methylene blue degradation yield and determine the constant rate which was clearly affected by coupling architecture. The nanocomposite fabricated by the same proportions of GO and CNTs, 3.33%, exhibited the maximal degradation yield, 96.5%, in the dye solution with the initial concentration of 3.0 mg l−1. The characterizations based on X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy, and field emission scanning electron microscopy (FESEM) revealed that the functionalized CNTs could create the appropriate space between the graphene sheets for uniformly interconnection of anatase via oxygen-containing groups onto the material surfaces. This enhancement in the degradation efficiency could be ascribed to the unique architecture, leading to a decrease in bandgap energy, 2.2 eV, which facilitated the electron-hole separation. Besides of breakthrough in the photoreaction rate, the adequate architecture led to an efficient reduction in the content of carbon-based materials. Also, the performance of mentioned nanocomposite under sunlight photons was effectively higher than that under UV irradiation. The hybrid nanocomposite provided a large number of active sites for photoreactions to facilitate the treatment of wastewater under solar irradiation.