Probability risk assessment of soil PAH contamination premised on industrial brownfield development: a case from China

Abstract

The harm of polycyclic aromatic hydrocarbons to human health and the natural environment has become an indisputable fact. Compared with other pollutants, PAHs are more toxic at low environmental concentrations, especially in industrialized environments. This study investigated the concentration distribution of soil PAHs at a well-known industrial production site in China and applied the Monte Carlo simulation method to assess the risk of cancer caused by the excessive accidental intake of PAHs in brownfield development environments. The results showed that the PAH content of the soil at the study site exceeded the local soil quality background value to varying degrees, and the excess rate ranged from 0.72 to 22.3%. There are serious health risks of BaP at the site, which has a 95th health risk percentile value of 1.12E-04. Those for BbF, InP, and DBA range from 1.0×10−6 to 1.0×10−4, and potential health risks occur. Moreover, the exposure duration and average carcinogenic time were the most influential parameters. The study has revealed that exposure to brownfield soil contaminated with PAHs increases the health risks. This is a representative study on the occurrence and concentration of PAHs in industrial brownfields in China, which can be adopted as a basis and evidence for pollution risk assessment of brownfield development.