Factors affecting the occurrence of lead and manganese in untreated drinking water from Atlantic and Gulf Coastal Plain aquifers, eastern United States—Dissolved oxygen and pH framework for evaluating risk of elevated concentrations

Abstract

Abstract Groundwater samples collected during 2012 and 2013 from public-supply wells screened in the Atlantic and Gulf Coastal Plain aquifers of the eastern and southeastern U.S. rarely contained lead or manganese concentrations that exceeded drinking-water limits, despite having corrosive characteristics. Data indicate that the occurrence of dissolved lead and manganese in sampled groundwater, prior to its distribution or treatment, was related to several explanatory factors including the presence of source minerals, hydrologic position along the flow path, water-rock interactions, and associated geochemical conditions such as pH and dissolved oxygen (DO) concentrations. Elevated concentrations of lead compared to health-based benchmarks were associated with groundwater that is acidic (pH\u202f≤\u202f6.5), oxygenated (DO\u202f≥\u202f2\u202fmg/L), and closer to recharge zones (relatively young water). Elevated concentrations of manganese were associated with groundwater that is acidic to neutral (pH\u202f≤\u202f7.5), has low DO (