Sulfonated poly(ether ether ketone) reinforced with polystyrene sulfonic acid functionalized micelle templated mesoporous MCM-41 for direct methanol fuel cells

Abstract

Abstract A composite membrane comprising sulfonated polyether ether ketone (sPEEK) and polystyrene sulfonic acid functionalized micelle templated MCM-41 (PSSA-f-MCM-41) is realized as a potential alternative to the Nafion membrane for direct methanol fuel cells (DMFC). PSSA-f-MCM-41 incorporation in sPEEK leads to improvement in the physio-chemical properties such as ionic conductivity, methanol permeability, tensile strength, water uptake and ion exchange capacity. The methanol permeability of the composite membrane i.e. PSSA-f-MCM-41 (1.5\xa0wt %)-sPEEK is reduced by 60% in comparison to pristine sPEEK. Moreover, the electrochemical selectivity of the aforesaid composite membrane is four times higher than sPEEK. The DMFC performance shows the peak power density of 147\xa0mW\xa0cm−2 for the composite membrane which is higher than the pristine sPEEK and Nafion 117 membranes. Stability test for the composite membranes confirm less degradation in OCV in comparison to pristine sPEEK.