Journal of Alloys and Compounds | 2019
A boron nitride-polyvinylidene fluoride-co-hexafluoropropylene composite gel polymer electrolyte for lithium metal batteries
Abstract
Abstract A modified gel polymer electrolyte (GPE) with boron nitride (BN) additive was designed to boost the electrochemical performance of rechargeable lithium metal battery, which consists of Li-rich layered cathode and possesses a high energy density. BN, electron insulator and ion conductor, has excellent thermodynamic and electrochemical stability. BN particles were well dispersed in polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) polymer matrices and thus substantially enhanced the electrochemical and physical properties of the GPEs. With only 0.5\u202fwt% BN additive, it remarkably improved the mechanical modulus and ionic conductivity (to 4.1\u202f×\u202f10−4\u202fS∙cm−2) of GPEs, which was beneficial for suppressing lithium dendrite formation and fast ion transportation, respectively, thereby enabling high-performance lithium metal batteries with ultra-long cycle life and high safety at ambient temperature (25\u202f°C) and high temperature (55\u202f°C).