Very high loading oxidized copper supported on ceria to catalyze the water-gas shift reaction

Abstract

Abstract To prepare supported catalysts with high loading and high dispersion of active metals is a crucial challenge in heterogeneous catalysis. Here we report the fabrication of very reactive catalyst that contains finely dispersed copper with 20 wt. % content supported on high-surface area CeO2 for the water-gas shift (WGS) reaction. This copper-ceria catalyst shows superb activity with a CO consumption rate of 116.7 μmolCO gcat-1 s-1 at 300 ℃, nearly one order of magnitude more active than other copper-based catalysts ever reported. Based on the precise and integrated\xa0characterizations, the oxidized not the metallic Cu are proved to be active centers where the adsorbed CO directly reacted with bridged —OH groups to finish the WGS reaction. The oxidized Cu sites are confirmed to be originated from the activation effect from Cu to CeO2, which promotes the oxygen of CeO2 diffuse from the bulk to surface, making Cu oxidized even under reductive atmosphere.