A new focus on the structure and mechanics of CuO-modified P2O5-V2O5 glasses

Abstract

Abstract Glasses in the system xCuO-(80-x)V2O5-20 P2O5 with x= 0- 40 mol %. have been prepared. XRD spectroscopy confirms the amorphous nature of all as-prepared compositions. 51V NMR experiments confirm increasing of nonbridging oxygen atoms (NBO) with increasing CuO. Ultrasonic velocities, both longitudinal and shear velocities decrease as CuO increases. CuO creates void spaces, causing the host network structure to weaken. The decreasing trends in both glass hardness numbers and ultrasonic longitudinal and shear velocities support that CuO enters the network to form NBO. The density increased significantly as the CuO content increased, while the molar volume decreased. Scanning electron microscopy (SEM) showed the creation of clusters species since Cu ions accumulation can be formed. Both (Cu2O) and (CuO) are the two stable copper oxide compositions in the bulk (CuO). Clusters, on the other hand, may be made up of a variety of stable components.