A green and efficient acid system for carbonate reservoir stimulation

Abstract

Abstract Matrix acidizing is a well stimulation method that is applied to enhance productivity. The success of a stimulation job depends mainly on the efficiency of the acid systems that are employed. This study investigated a new and efficient acid system that is biodegradable, not corrosive, and safe to handle. The system efficiency was compared to that of HCl and chelating agents. Acid coreflooding has been applied to chalk, dolomite, and limestone carbonate rock samples to measure the efficiency in terms of injected pore volume to breakthrough (PVBT). The rock samples were characterized in terms of porosity, permeability, composition using X-ray diffraction (XRD), and pore distribution using nuclear magnetic resonance (NMR). The effluent was collected at different times and analyzed using induced coupled plasma (ICP). Medical computed tomography (MCT) was used to visualize the interior of the rock samples after acidizing. The new acid system was more efficient in terms of acid spending than straight HCl acid and chelating agents in Indiana limestone. At the optimum injection rate, chelating agents had an optimum PVBT value of about 15 compared to 0.85 for plain HCl acid. Using the new acid system resulted in an optimum PVBT value of only 0.41, which is less than half of HCl acid. A numerical wormhole simulator was implemented to match the experimental PVBT and assess the reactivity of the acid system.