Species distribution in laser-induced plasma on the surface of binary immiscible alloy

Abstract

Abstract Investigation on species distribution of vapor plasma is of great significance for understanding the laser-target interaction, the plasma dynamics and verifying theoretical models. It is also helpful for optimizing the spectral acquisition to improve the quantitative performance of spatial-resolved laser-induced breakdown spectroscopy (LIBS). In this work, the laser-induced plasma on the surface of binary alloy is analyzed by using spectrally, spatially and temporally resolved dual-wavelength differential imaging to explore the dependence of species distribution in plasma on laser-supported absorption (LSA) wave regime and sample composition. The laser-supported combustion (LSC) and laser-supported detonation (LSD) wave dominated plasmas with different elemental mass ratios are induced from a series of binary immiscible alloys by using low and high irradiance laser pulses, respectively. By comparing the spatial-temporal emissivity images of species, the following conclusions are drawn: 1) laser irradiance can change the species distribution of plasma, while the sample composition cannot; 2) for LSC-wave dominated plasma, the species distribution mainly depends on the melting points of constituted elements in the sample, while for LSD-wave dominated plasma, it mainly depends on the atomic masses of elements. The above behaviours on species distribution in plasma produced from binary immiscible alloys are expected to be suitable for other elements or even multi-element plasmas.