Decorating graphene oxide with zeolitic imidazolate framework (ZIF-8) and pseudo-boehmite offers ultra-high adsorption capacity of diclofenac in hospital effluents.

Abstract

This study reports on an easy and scalable synthesis method of a novel magnetic nanocomposite (GO/ZIF-8/γ-AlOOH) based on graphene oxide (GO) nanosheets decorated with zeolitic imidazolate framework-8 (ZIF-8), pseudo-boehmite (γ-AlOOH), and iron oxide (Fe3O4) nanoparticles by combining solvothermal and solid-state dispersion (SSD) methods. The nanocomposite was successfully applied to remove of diclofenac sodium (DCF) - a widely used pharmaceutical - from water. Response Surface Methodology (RSM) was used to optimize the adsorption process and assess the interactions among the influencing factors on DCF removal efficiency; including contact time, adsorbent dosage, initial pH, solution temperature, and DCF concentration. Adsorption isotherm results showed a good fitting with the Langmuir isotherm model with an exceptional adsorption capacity value of 2594\xa0mg\xa0g-1 at 30\xa0°C, which was highly superior to the previously reported adsorbents. In addition, kinetic and thermodynamic investigations further illustrated that the adsorption process was fast (equilibrium time\xa0=\xa050\xa0min) and endothermic. The regeneration of GO/ZIF-8/γ-AlOOH nanocomposite using acetic acid solution (10% v/v) after a simple magnetic separation was confirmed in five consecutive cycles, which eliminate the usage of organic solvents. The nanocomposite has also shown a superior performance in treating a simulated hospital effluent that contained various pharmaceuticals as well as other organic, and inorganic constituents.