State-of-the-art and prospects of Zn-containing layered double hydroxides (Zn-LDH)-based materials for photocatalytic water remediation.

Abstract

With the rapid worldwide development of industry and human activities, increasing amounts of multifarious contaminants have significantly threatened environmental ecosystems and human health. Solar photocatalytic decontamination, as an environmentally friendly technology, has been regarded as a good approach to eliminate water pollutants. To date, various photocatalysts have been developed for the purpose of water remediation. Zn-containing layered double hydroxides (Zn-LDHs) and their derivatives are promising candidates due to their suitable band edge positions (oxidation-reduction potentials) for high photocatalytic performances, flexible properties derived from adjustable components and tailorable electronic structures, chemical stabilities, and low toxicities. This review focuses on the fabrication and modification of Zn-LDHs and their photocatalytic applications for the elimination of contaminants in water, including the degradation of toxic organic pollutants, transfer of hazardous heavy metals to lower toxicity heavy metals, and bacterial inactivation. The mechanisms involved in the photocatalytic processes are also thoroughly reviewed. Finally, the emerging scientific and engineering opportunities and challenges in environmental photocatalysis are presented. This review provides basic insights into the construction of Zn-LDH-based materials with high photocatalytic activities and new perspectives on their applications for the photocatalytic elimination of contaminants, which is helpful for the development of photocatalysis for environmental remediation from the lab to industry.