Kinetic behavior of heterogeneous sorption deformation on coal: Effect of maceral/micro-lithotype distribution

Abstract

Abstract The greenhouse effect has attracted increasing attention globally. The geologic sequestration of CO2 is considered as an effective method for reducing the amount of CO2 in the atmosphere. Carbon-dioxide enhanced coalbed methane (CO2-ECBM) recovery is extremely attractive owing to its ability to store CO2 in coal seams while simultaneously enhancing the production of methane. However, the injection of CO2 can induce a deformation of the coal matrix, which has a significant effect on the fluid flow and stability of the coal seams. In this study, the sorption kinetics experiments indicated the high anisotropy and heterogeneity of local sorption deformation in coal samples and a unique kinetic behavior of sorption deformation which was rarely reported and analyzed in detail in previous studies. This kinetic behavior demonstrated a rapid increase of sorption strain followed by a slight or significant falloff until the equilibrium state reached. The characteristics of component distribution in coal samples were investigated using CT scanning and micro-lithotype and EDS analysis. An extensive analysis of the experiment results indicated the following: 1) Carbon dioxide dissolved during the first sorption process induced a rearrangement of the coal structure, leading to a drastic variation of deformation behavior between the first and subsequent sorption process. 2) The unique kinetic behavior of sorption deformation could be induced by either the loss of moisture in coal or the interaction of different coal components. The mechanism of these two factors induced coal shrinkage was different and had a distinct effect on the global behavior of sorption deformation. 3) The quantitative relationship between compressional and dilative components directly verified the significant compression of inertinite-rich regions by the slow swelling of vitrinite-rich regions. 4) The kinetic behavior of sorption deformation was affected by the combination of the macroscopic bedding structure and the heterogeneous component distribution in coal.