Rapid and sensitive determination of nitrobenzene in solutions and commercial honey samples using a screen-printed electrode modified by 1,3-/1,4-diazines.

Abstract

In this work, a screen-printed electrode (SPE) modified by 1,3/1,4-diazines was prepared for the rapid and sensitive determination of nitrobenzene (NB). The obtained results indicated enhanced cathodic currents of direct NB reduction into hydroxylaminophenol on the diazine-modified SPEs. The enhanced effect was most likely due to the combination of complexation and collisional processes of diazines towards nitroaromatic compounds and also the diazine-modified electrodes increased electroconductivity. The best electrochemical responses were obtained in square wave voltammetry mode by using the carbazolyl substituted diazines as a component of the sensitive layer, which was assembled by co-electropolymerization with the unsubstituted carbazole on the electrode during 5 cycles. The low detection limit estimated as 0.107\xa0μM and wide linear range (1-1000\xa0µM) enables NB in water and food samples to be determined. The developed modified electrode was applied in the analysis of commercial honey samples.