Adsorption and oxidation of ciprofloxacin in a fixed bed column using activated sludge derived activated carbon.

Abstract

In this study, the performance of activated sludge derived granular activated carbon (SGAC) was investigated for ciprofloxacin (CPX) removal from synthetic and simulated wastewaters in a fixed-bed adsorption column operated in continuous mode. The adsorbent was synthesized using chemical activation using ZnCl2 as activating agent. Its surface area and pore volume were found comparable to that of the commercial granular activated carbon (CGAC). The maximum saturation adsorption capacities for CPX were ~16\u202fmg/g and ~14\u202fmg/g, respectively, with SGAC column under identical operating conditions (CPX concentration\u202f=\u202f50\u202fmg/L, bed height\u202f=\u202f4\u202fcm and wastewater flow rate\u202f=\u202f1.5\u202fmL/min) for synthetic and simulated wastewaters. The presence of other organics reduced CPX adsorption capacity of SGAC. The breakthrough curve data for both wastewaters could be adequately fit in Thomas and Yoon-Nelson kinetic models. The addition of H2O2 in wastewater showed no considerable improvement in CPX removal. However, H2O2 oxidation of spent adsorbent exhibited better results compared to thermal treatment for adsorbent regeneration. The results showed that sewage sludge can be recycled as an efficient adsorbent for the removal of recalcitrant organic pollutants from wastewater.