Thermochemical interactions between CMAS and Ca2Y8(SiO4)6O2 apatite environmental barrier coating material

Abstract

Abstract Thermochemical interactions between Ca2Y8(SiO4)6O2 apatite, a potential environmental barrier coating (EBC) material, and a synthetic CMAS having the composition 23.3 CaO - 6.4 MgO - 3.1 Al2O3 - 62.5 SiO2 - 4.1 Na2O - 0.5 K2O - 0.04 Fe2O3 mole % were investigated. Pellets of apatite\u202f+\u202fCMAS powder and hot-pressed apatite disc-CMAS couples were annealed at 1200–1500\u202f°C for 1–50\u202fhours in air. Powder X-ray diffraction (XRD) was used to identify the phases present. Polished cross-sections of the heat treated pellets and diffusion couples were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), high angle annular dark field (HAADF) imaging, selected area electron diffraction (SAED), and energy dispersive X-ray spectroscopy (EDS). Ca3Y2(Si3O9)2 cyclosilicate, apatite, and amorphous phases were present in the samples heat treated at 1200 and 1300\u202f°C, whereas no cyclosilicate was detected in samples annealed at 1400 and 1500\u202f°C. A distinct cyclosilicate layer was observed at the apatite-CMAS interface in the diffusion couples heat treated at 1200 and 1300\u202f°C. However, at 1400 and 1500\u202f°C, due to its much lower viscosity, CMAS quickly infiltrated the apatite substrate through pores and along the grain boundaries and no cyclosilicate was observed; the apatite grains dissolved in molten CMAS followed by re-precipitation of apatite needles within an amorphous phase on cooling.