Non-thermal plasma combined with zeolites to remove ammonia nitrogen from wastewater.

Abstract

In this work, non-thermal plasma combined with zeolites was used to remove inorganic pollutant ammonia nitrogen from wastewater. Ammonia nitrogen elimination performances at various operating parameters were investigated. Roles of active species in the removal of ammonia nitrogen were also discussed. The experimental results showed that 69.97% ammonia nitrogen can be removed from the plasma/zeolites synergistic system after 30 min treatment. The removal efficiency was 16.23% and 61.55% higher than that in sole zeolites adsorption system and that in sole discharge plasma system, respectively. Higher applied voltage, lower initial ammonia nitrogen concentration and weak acidic conditions were favorable for ammonia nitrogen removal. After the addition of zeolites, part of O3 and H2O2 generated in the plasma/zeolites system were decomposed into other oxygen species (•OH and 1O2), which improved the oxidation degree of ammonia nitrogen. In addition, the reaction mechanism of ammonia nitrogen in water by plasma/zeolites process was discussed. After repeated use three times, the effect of the zeolites in the plasma/zeolites system remained stable. Characterization of the zeolites after reaction was analyzed through BET, SEM, XRD and FT-IR. The experiments have confirmed the applicability of the plasma/zeolites system for the further treatment of low-concentration ammonia nitrogen wastewater.