Effects of cellulose/salicylaldehyde thiosemicarbazone complexes on PVA based hydrogels: Portable, reusable, and high-precision luminescence sensing of Cu2.

Abstract

Novel portable, high-precision, and reusable fluorescent polyvinyl alcohol (PVA)-borax hydrogel sensors were prepared to detect Cu2+ in aqueous environment. A TEMPO-oxidized cellulose nanofibers/salicylaldehyde thiosemicarbazone (TOCN/ST) complex was further incorporated into the PVA-borax matrix. The in situ polymerization of TOCN/ST complex enhanced the mechanical properties of the hydrogels and improved the accuracy of detection. The resultant hydrogels were thermo reversible, and it converted to the liquid state during heating, which could greatly reduce the deviations caused in the detection of solid sensors. After cooling, the hydrogel could transform into the solid condition, which was easily portable. The sensor induced a significant luminescence quenching to the Cu2+ at 485 nm, with a detection limit of 0.086 μM. In the presence of ethylenediaminetetraacetic acid disodium, Cu2+ were tightly seized, causing the liberation of TOCN/ST complex and thus, a reversible ON-OFF-ON fluorescence behavior was displayed. The fluorescence intensity was maintained at 82 % after 10 uses, and the mechanical strength was maintained at 85 % after 3 uses. The anti-bacterial activity test also confirmed the TOCN/ST complex was extremely potent in suppressing the growth and reproduction of Escherichia coli. The proposed hydrogel provides a new insight into the detection of Cu2+ in aqueous environments.