Cadmium removal by FeOOH nanoparticles accommodated in biochar: Effect of the negatively charged functional groups in host.

Abstract

Metallic oxide nanoparticles (NPs) anchored in biochar provide a promising measure forward into the scaled-up application of these NPs in water treatment, and reducing the size of the dwelled NPs is expected to boost the adsorption performance of biochar-based composites because of the size and surface effect. Nevertheless, it is still of great challenge to regulate the size of the impregnated NPs due to their intrinsic self-agglomeration caused by high surface energy. In this study, we fabricated the charged biochar (C-BC) bearing high-density negatively charged groups (i.e., carboxyl and hydroxyl groups) via HNO3 oxidization to load the model metal oxide FeOOH NPs. The average sizes of anchored FeOOH NPs were ultrasmall, ranging from 19.9\xa0±\xa01.5 to 3.1\xa0±\xa00.5\xa0nm, and decreased with the increased amount of carboxyl and hydroxyl groups in C-BC. Whether in batch adsorption or fixed-bed column setting, adsorption of Cd(II) onto the as-made composites was greatly enhanced by carboxyl and hydroxyl groups in carrier. The normalized adsorption capacities of Cd(II) by ferric mass of the loaded FeOOH were 499.9-724.9\xa0mg/g-Fe, approximately 18.6-27.1 and 2.51-3.64 folds over the bulky FeOOH and FeOOH-impregnated biochar. Our study results should provide a significant reference on how to acquire highly efficient biochar-based composites for water decontamination.