Characteristics and secondary formation of water-soluble organic acids in PM1, PM2.5 and PM10 in Beijing during haze episodes.

Abstract

Water-soluble organic acids are widely involved in various atmospheric physicochemical processes and appear as an important fraction of atmospheric aerosols. Nineteen water-soluble organic acids in 12-h PM1, PM2.5 and PM10 samples collected in urban Beijing during haze episodes in winter and spring of 2017 were identified to investigate their characteristics and secondary formation mechanism. The molecular distributions of water-soluble organic acids as well as the high ratio of phthalic acid (Ph)/azelaic acid (C9) indicated severe aromatic secondary organic aerosol pollution during the haze episodes, especially in winter. The diurnal patterns, size distributions, and concentration ratios of specific organic acids were investigated to reveal the pollution characteristics and possible sources of major organic acids in particulate matter in Beijing during haze events. Multiple linear regression was used to tentatively quantify the relative contributions of photochemical oxidation and aqueous-phase oxidation to the formation of total water-soluble organic acids in PM1, PM2.5 and PM10 during haze episodes. The formation mechanism of sulfate and nitrate was also investigated for comparison. Different from the secondary formation of sulfate, the secondary formation of water-soluble organic acids showed enhanced contribution of gas-phase photochemical oxidation though the aqueous-phase oxidation was the dominant process. CAPSULE: Molecular analyses of organic acids in PM1, PM2.5 and PM10 in Beijing during haze periods revealed their pollution characteristics, possible sources and formation mechanism.