Abatement of NO/SO2/Hg0 from flue gas by advanced oxidation processes (AOPs): Tech-category, status quo and prospects.

Abstract

This review article provides a state-of-art insight into the removal of NO, SO2 and elemental mercury (Hg0) from flue gas by using advanced oxidation processes (AOPs) method. Firstly, the main flue gas purification strategies based on AOPs would be classified as gas-gas, gas-liquid and gas-solid systems preliminarily, and the primary chemistry/mechanism of the above homogeneous/heterogeneous reaction systems were presented as the oxidation of NO, SO2 and Hg0 by the oxidative free radicals (OH, O2 and SO4-etc.). Secondly, the research progress and reaction pathways for separately or simultaneously removing NO, SO2 and Hg0 from flue gas by AOPs has been reviewed elaborated and analyzed in more details. Notably, the wet/dry oxidation coupled with efficient absorption process would be a promising method of efficient removal of above gaseous pollutants. Subsequently, four types of assumed layout modes were described graphically. The application prospects of AOPs for the purification of flue gas from coal-fired boiler or industrial furnace were evaluated and found that the operation cost and utilization of oxidants must be reduced and improved respectively. Finally, the limitations in the current removal technologies based on AOPs are highlighted, meanwhile the future research directions are suggested, such as cut down the cost of oxidants and catalysts, improve the yield and valid utilization of highly reactive radicals and enhance the reactivity, resistance and stability of catalysts. Significantly, it is also envisaged that the review could enrich the knowledge repository to function as a scientific reference for the sustainable development of economical, effective and environment-friendly technologies for the abatement of a wide variety of emissions from flue gas, and further improve the feasibility and reliability of the strategies for moving from laboratory studies to large-scale development and industrial application.