A Highly Reactive Chromium(V)–Oxo TAML Cation Radical Complex in Electron Transfer and Oxygen Atom Transfer Reactions

Abstract

We report the synthesis, characterization, and electron-transfer (ET) oxidation reactivity of a chromium(V)–oxo TAML cation radical complex binding Sc3+ ion, {[CrV(O)(TAML•+)]-Sc3+}3+ (2-Sc). Its p...