Polyvinylalcohol (PVA)-Assisted Exfoliation of ReS2 Nanosheets and the Use of ReS2-PVA Composites for Transparent Memristive Photosynapse Devices.

Abstract

Two-dimensional (2D) transition metal dichalcogenides (TMDs) have attracted significant attention for their outstanding optoelectrical properties. Unlike most TMDs with layer-dependent photoresponsivity, rhenium disulfide (ReS2) shows excellent thickness-independent photoresponsivity. Herein, we show a surfactant-free polyvinyl alcohol (PVA)-assisted exfoliation method for 2D-TMDs in aqueous solution and a transparent photosensitive memristor synapse device based on ReS2 nanosheets composited with PVA. ReS2 nanosheets are obtained via PVA-assisted exfoliation. After exfoliation, the ReS2-PVA dispersion solution is spin-coated on a substrate and dried to form a nanocomposite film without additional processing. Transparent memristors are then fabricated on plastic or glass substrates to demonstrate the applicability of the ReS2-PVA film. The devices show write once, read many memory behavior with a high ON/OFF current ratio (1.0 × 104 at 0.5 V) during electrical operation. In the high resistive state, synaptic functions with long-term memory behavior are successfully mimicked by applying photonic stimuli to the transparent ReS2-PVA memristors. The excitatory postsynaptic current stimulated by the photosignal is gradually reduced by electric stimuli. The proposed PVA-assisted exfoliation method is cost-effective, environmentally friendly, and applicable to various TMD nanomaterials. Furthermore, the ReS2-PVA nanocomposite film obtained via a simple solution-based process demonstrates excellent photosynaptic behavior.