Water-Chloroform Interface Assisted Microstructure Tuning of Polypyrrole-Silver Sheets.

Abstract

The liquid-liquid interface of two immiscible solvents remarkably controls the morphology of polymeric nanostructures as compared to the polymerization in single solvent systems. The polymerization of pyrrole in the water-chloroform medium using silver nitrate (AgNO3) as oxidant yields polypyrrole/silver (PPy/Ag) sheets. The water-chloroform interface acts as a template for the growth of PPy/Ag hybrids into sheets by preventing the secondary growth of silver associated pyrrole oligomers in a three-dimensional (3-D) manner. On the contrary, the 3-D growth of pyrrole oligomers into spherical shapes at the water-chloroform interface is observed when ammonium persulfate (APS) is used as the oxidant. Transmission electron microscopic and scanning electron microscopic images reveal the sheetlike morphology of PPy/Ag with a relatively uniform distribution of Ag NPs (∼100 nm) on PPy sheets. The ratio of aqueous-organic bisolvent and the concentration/type of oxidant have a distinct effect on morphology, crystallinity, and electrical properties of PPy/Ag sheets. The dispersed PPy/Ag sheets are stable in moderately polar solvents up to 2 weeks. The electrochemical behavior of PPy/Ag sheets is confirmed by H2O2 sensing capability through cyclic voltammetry experiments. The antibacterial activity toward E. coli and S. aureus is quantitatively assessed using the minimum bactericidal concentration (MBC) determination.