Carbon Nanotubes Readily Disperse in Linear Silicones and Improve the Thermal Stability of Dimethylsilicone Elastomers.

Abstract

Silicone fluid - carbon nanotube stable dispersions were prepared in minutes by simple mixing processes, without the addition of solvents or surfactants and without chemical modification of the nanotubes. With linear silicones of sufficient viscosity, a dual asymmetric centrifuge (speedmixer) was sufficient for dispersion; lower viscosity silicones required brief ultrasound treatment. Optical microscopy indicates homogeneous dispersion of multiwalled carbon nanotube (MWCNT) bundles in linear poly(dimethylsiloxane) (PDMS) oils. The facile dispersion of carbon nanotubes in PDMS has been reported in several previous publications and this appears to be general for silicones. MWCNTs also disperse readily, and to a greater extent as assessed by optical microscopy, in poly(methylphenylsiloxane) and, in particular, poly(diethylsiloxane). Linear PDMS/MWCNT dispersions are stable from agglomeration for months. Platinum-catalyzed hydrosilylation of MWCNT-containing vinyl/hydride-functionalized PDMS liquids yielded filled elastomers that unexpectedly exhibit significantly increased thermal stability. This enhancement occurs with only fractions of a weight percent of MWCNTs. Thermal gravimetric analysis shows a 54 °C increase in peak weight loss temperature (446 °C to 500 °C), an increased decomposition activation energy (158 kJ/mol to 233 kJ/mol), a second higher temperature decomposition process, and doubled char formation (20% to 40%) with only 0.5 wt% added MWCNT. Pyrolysis Combustion Flow Calorimetry (PCFC) confirmed the enhancement in thermal stability. Improvements in electrical conductivity were observed at loadings as low as 0.025 wt%. Spontaneous adsorption of dialkylsiloxane chains to MWCNT surfaces (wetting) and the resulting changes in composite structure are implicated as the basis for dispersion and thermal behavior changes.