Atomic-scale combination of germanium-zinc nanofibers for structural and electrochemical evolution

Abstract

Alloys are recently receiving considerable attention in the community of rechargeable batteries as possible alternatives to carbonaceous negative electrodes; however, challenges remain for the practical utilization of these materials. Herein, we report the synthesis of germanium-zinc alloy nanofibers through electrospinning and a subsequent calcination step. Evidenced by in situ transmission electron microscopy and electrochemical impedance spectroscopy characterizations, this one-dimensional design possesses unique structures. Both germanium and zinc atoms are homogenously distributed allowing for outstanding electronic conductivity and high available capacity for lithium storage. The as-prepared materials present high rate capability (capacity of ~\u200950% at 20\u2009C compared to that at 0.2 C-rate) and cycle retention (73% at 3.0 C-rate) with a retaining capacity of 546\u2009mAh\u2009g−1 even after 1000 cycles. When assembled in a full cell, high energy density can be maintained during 400 cycles, which indicates that the current material has the potential to be used in a large-scale energy storage system.Alloy anode materials are receiving renewed interest. Here the authors show the design of Ge-Zn nanofibers for lithium ion batteries. Featured by a homogeneous composition at the atomic level and other favorable structural attributes, the materials allow for impressive electrochemical performance.