Atomic iridium@cobalt nanosheets for dinuclear tandem water oxidation

Abstract

Atomization of noble metals enable their electrocatalysis applications with low cost, whereas the isolated mononuclear site after atomization might lead leads to limited performance. Herein, we present a general strategy of atomically confined alloying (ACA) to synthesize an electrocatalyst of single atom iridium-trapping cobalt nanosheets with dual-reactive Ir–Co sites. The atomic Ir@Co nanosheets (1.7 wt% Ir) exhibit excellent oxygen evolution reaction (OER) performance with a small overpotential (273 mV at 10 mA cm−2) and high stability, higher than that of the Ir/C catalyst (290 mV at 10 mA cm−2). More importantly, density functional theory (DFT) calculations combined with experiments demonstrated that water oxidation proceeded on atomic Ir@Co nanosheets via a dinuclear tandem mechanism, in which Ir–Co dual sites cooperatively worked in favour of the sequential transfer from Co–OH* to Ir–O* via a Co–O–Ir intermediate, and stabilization of OOH* species by hydrogen bonding interaction. The cooperative mechanism based on a dinuclear electrocatalyst by ACA is hoped to open up more possibilities of single atom noble metal electrocatalysts for various applications.