Rh(iii)-Catalyzed [3 + 2]/[4 + 2] annulation of acetophenone oxime ethers with 3-acetoxy-1,4-enynes involving C–H activation

Abstract

A novel, synthetically simple, selective rhodium(iii)-catalyzed [3 + 2]/[4 + 2] annulation cascade reaction to construct complex azafluorenone frameworks has been developed.