Chemical Science | 2019
Influence of structure–activity relationships on through-space intervalence charge transfer in metal–organic frameworks with cofacial redox-active units† †Electronic supplementary information (ESI) available. CCDC 1585897 and 1585898. For ESI and crystallographic data in CIF or other electronic form
Abstract
Metal–organic frameworks incorporating cofacially-aligned redox-active ligands exhibit through-space intervalence charge transfer phenomena.