Chemical communications | 2019
NO sorption, in-crystal nitrite and nitrate production with arylamine oxidation in gas-solid single crystal to single crystal reactions.
Abstract
A bridging nitrite and a nitrate counter anion per Co2 site are generated in-crystal and an arylamine group on the ligand scaffold is oxidised to a nitro group when nitric oxide (NO) is chemisorbed by molecular crystals of cobalt complexes.