Quantum dynamics of the energy transfer for vibrationally excited HF (v = 7) colliding with D2 (v = 0): Theory assessing experiment.

Abstract

It is still challenging to accurately qualify the rate coefficients for vibrationally excited molecules in experiment. In particular, for the energy transfer between HF (v = 7) and D2 (v = 0), which is a prototype for near resonant collisional transfer of vibrational excitation from one molecule to the other, the two available experimental results of rate coefficients contradict each other by a factor of nearly 20. In order to benchmark these data, in this work, the rate coefficients of vibration-vibration energy transfer processes of this system at temperatures ranging from 100 to 1500 K were calculated by employing the coupled-states approximation based on our recently developed full-dimensional ab initio intermolecular potential energy surface. The state-to-state rate coefficients were found to follow the general energy gap law. The calculated total vibration-vibration energy transfer rate coefficients decrease with the increase in the angular momentum of HF at most temperatures. The vibrational relaxation rate coefficient decreases monotonously with the temperature, and the calculated result of 8.1 × 10-11 cm3 mol-1 s-1 at room temperature is in very good agreement with the experimental value reported by Dzelzkalns and Kaufman [J. Chem. Phys. 77, 3508 (1982)].