Voltage boost effects in two-step photon upconversion solar cells with a modulation-doped structure

Abstract

A two-step photon upconversion (TPU) solar cell is a single-junction solar cell with a suitably designed heterointerface in the intrinsic layer. At this interface, upconversion can take place by absorbing infrared light, which excites carriers to energies above the heterojunction barrier, and then an electric field extracts these upconverted carriers to the barrier material. In this work, we study this photoabsorption process in a TPU solar cell with a modulation-doped structure. The modulation doping technique enables us to control the electric field at the heterointerface, and we demonstrate that the efficiency of the TPU process strongly depends on the electric field at the heterointerface. While we show that the TPU process induced by infrared light leads to a significant increase in the external quantum efficiency, we also note that this TPU process is an adiabatic process. It is shown that the adiabatic intraband photoexcitation at the heterointerface is able to increase the open-circuit voltage even above the open-circuit voltage that we predict from the diode equation and the actual current increase. We demonstrate obvious voltage boost effects and elucidate the relationship between the current and voltage.