Expansionless oxidation-bonded SiC microfiltration membrane by controlling the oxidation of SiC particle mixtures

Abstract

ABSTRACT Oxidation bonding is a technique used to produce porous SiC ceramics at low temperatures. The oxidation behavior of SiC particles depends on various factors, including the oxidation environment, temperature, time, particle size, and impurities. The key properties required for a porous ceramic membrane are a controlled pore morphology, high strength, and high permeability. In this study, SiC powders with different particle sizes (0.55 and 7 μm) were used to fabricate porous ceramic membranes. First, the oxidation behavior of the SiC powders was evaluated. Then, the feasibility of using their mixture to create supports for microfiltration applications was analyzed. Through this study, not only were the ideal conditions for fabricating microfiltration supports quantified but also the conditions where specimens could be made with zero size change. Finally, a membrane fabricated from a powder mixture composed of 92% of the 7 μm powder and 8% of the 0.55 μm powder and sintered at 1450°C was proposed, which had a 37% porosity, 1.42 μm pore size, 49.6 MPa flexural strength, and L cm-2 min-1 bar-1 air permeability.