Morphology and kinetics of random sequential adsorption of superballs: From hexapods to cubes.

Abstract

Superballs represent a class of particles whose shapes are defined by the domain |x|^{2p}+|y|^{2p}+|z|^{2p}≤R^{2p}, with p∈(0,∞) being the deformation parameter. 01 represent, respectively, families of convex octahedral-like and cubelike particles, with p=1,0.5, and ∞ representing spheres, octahedra, and cubes. Colloidal zeolite suspensions, catalysis, and adsorption, as well as biomedical magnetic nanoparticles are but a few of the applications of packing of superballs. We introduce a universal method for simulating random sequential adsorption of superballs, which we refer to as the low-entropy algorithm, which is about two orders of magnitude faster than the conventional algorithms that represent high-entropy methods. The two algorithms yield, respectively, precise estimates of the jamming fraction ϕ_{∞}(p) and ν(p), the exponent that characterizes the kinetics of adsorption at long times t, ϕ_{∞}(p)-ϕ(p,t)∼t^{-ν(p)}. Precise estimates of ϕ_{∞}(p) and ν(p) are obtained and shown to be in agreement with the existing analytical and numerical results for certain types of superballs.