Investigation of Laser Induced Graphene Electrodes Modified by MWNT/AuNPs for Detection of Nitrite

Abstract

In this paper, a novel low cost electrode material for electrochemical sensing is presented which demonstrates excellent electrochemical response to nitrite while being amenable to implementation in disposable point of care nitrite sensors. Laser induced grapheneous carbon (LIG) is based on a simple laser engraving method to fabricate electrodes by inducing conductive paths onto Kapton polymer substrate. The working electrode was modified by Gold Nanoparticles (AuNPs), multiwalled carbon nanotubes (MWCNT) and AuNPs/MWCNT. The modified electrodes were characterized by electron microscopy coupled with energy x-ray dispersive spectroscopy (SEM-EDX), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Surface morphology and electrochemical methods confirms confirm the successful implementation of LIG electrodes whose electrocatalytic performance is highly improved after modification. This suggests the synergetic effect between AuNPs and MWCNTs with the excellent conductivity and large specific surface area. By means of square wave voltammetry (SWV), the limit of detection of the proposed sensor is $6.75\\ \\mu\\mathrm{M}$, which is low enough for practical applications. In conclusion, AuNPs/MWCNT modified LIG electrodes demonstrated good electrochemical behavior and promising future use in disposable nitrite electrochemical sensors.