Phase Transitions in SiO2 Nanopowder Synthesized by Electric Arc Plasma

Abstract

This article deals with the synthesis of the SiO2 nanopowder in the original plasma system including a water-cooled reactor, arc plasma jet, and feed unit. The operating principle of this electro-plasma system is based on gas evaporation and condensation of the molten material. A continuous material feeding into the plasma jet provides the high yield of the target product due to a complete evaporation of the condensed phase. This article presents the experimental results of the SiO2 nanoparticle synthesis from high-silica natural material and the investigation of the particle phase composition after the conventional thermal treatment. It is found that the average particle size is about 100 nm at a maximum 25-kW power of the plasma jet; amorphized bonds in the synthesized high-dispersive powder provide the formation of polydisperse clusters of particles. The powder heating up to 1173 K results in crystallization and grouping of the SiO2 nanoclusters. The high-dispersive SiO2 powder allows stabilizing the phase transition to a modification of SiO $_{2}\\alpha $ -tridymite that is not observed in the initial natural quartz.