Evaluation of Corrosion Inhibition Efficiency of Aluminum Alloy 2024 by Diaminostilbene and Azobenzene Schiff Bases in 1\u2009M Hydrochloric Acid

Abstract

The Schiff base compounds N,N\n \n \n \n \n ′\n \n \n \n -bis(salicylidine)-4,4\n \n \n \n \n ′\n \n \n \n –diaminostilbene(SDS) and N,N\n \n \n \n \n ′\n \n \n \n -bis(salicylidine)-4,4\n \n \n \n \n ′\n \n \n \n -diamino azobenzene(SDA) were synthesized, and their molecular structure was determined by FT-IR and 1H NMR. The corrosion inhibitions of Schiff base compounds on aluminum alloy 2024 in 1\u2009M hydrochloric acid were evaluated by potentiodynamic polarization, impedance techniques, weight loss method, and scanning electron microscopic technique. The potentiodynamic polarization (PDP) studies revealed that SDS and SDA compounds acted predominantly as cathodic inhibitors. The electrochemical impedance spectroscopic (EIS) parameters confirmed the adsorption of SDS and SDA molecules over the surface of aluminum alloy 2024 alloy by forming an inhibitive layer. The weight loss studies showed that the inhibition efficiency of these compounds increases directly with concentration and decreases with an increase in solution temperature and immersion time. The thermodynamic parameters were calculated to investigate the mechanism of corrosion inhibition. The SDA was found to be more effective than SDS and followed the Langmuir adsorption isotherm model. The scanning electron microscopy (SEM) results revealed that the deterioration of the alloy surface is minimal in the presence of an inhibitor. Both Schiff base molecules exhibited superior corrosion inhibition for aluminum alloy 2024 alloy in HCl medium.