Potential Source Regions and Transportation Pathways of Reactive Gases at a Regional Background Site in Northwestern China

Abstract

Reactive gases (O3, CO, NO2, and SO2) were collected hourly at the Akedala regional background station in northwestern China during September 2017 to August 2018. Wind rose, cluster analysis, potential source contribution function (PSCF), and concentration-weighted trajectory (CWT) methods were adopted for identifying the transport pathways and potential source regions of these atmosphere components at Akedala. The average O3, CO, NO2, and SO2 mixing ratios detected were 29.65\u2009±\u200911.44\u2009ppb, 123.78\u2009±\u200973.35\u2009ppb, 3.79\u2009±\u20090.98\u2009ppb, and 4.59\u2009±\u20090.88\u2009ppb during the observation period, and the statistical results of the monthly mean values revealed that there were differences during the highest pollution period, with O3 and CO mainly peaking in February, with mixing ratios of 38.03\u2009±\u20097.10\u2009ppb and 208.50\u2009±\u2009106.50\u2009ppb, respectively. Meanwhile, NO2 peaked in March (4.51\u2009±\u20090.54\u2009ppb) and SO2 in January (5.70\u2009±\u20091.92\u2009ppb). The most obvious diurnal variation of CO and SO2 was observed in the winter, with maximum levels reaching between 13\u2009:\u200900 and 14\u2009:\u200900. The diurnal variations of O3 exhibited low values during the night and maximum values in the afternoon (16\u2009:\u200900–18\u2009:\u200900). Diurnal variation was not significant in the case of NO2. Cluster analysis showed that six main paths affected the Akedala atmosphere. In turn, the PSCF and CWT analysis results indicated that the Akedala reactive gas was affected by both local and foreign sources. The high PSCF value of the reactive gas potential source areas appeared in eastern Kazakhstan, northern Xinjiang, Western Mongolia, and Southern Russia. The WCWT (weighted concentration-weight trajectory) values of CO and SO2 in winter were the highest, totaling 180–240\u2009ppb and 5–6.5\u2009ppb, respectively. The WCWT value of O3 in the spring and summer was higher than that in the autumn and winter. The main source area of O3 was about 32–36\u2009ppb in the spring and summer, and the main source area of NO2 in the summer had a low WCWT value of 3–3.5\u2009ppb, whereas the NO2 WCWT value was concentrated at 4–4.5\u2009ppb in the other seasons.