Reduction-resistant [Au25(cyclohexanethiolate)18]0 with an Icosahedral Au13 Core

Abstract

Cyclohexanethiolate-protected gold cluster Au25(c-HT)18 was isolated for the first time as a minor byproduct of [Au23(c-HT)16]−. Single-crystal X-ray structure analysis revealed that Au25(c-HT)18 h...